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Samsung CF391 series monitors 2016 vs LG UD5 series (2017)
The Samsung C32F391 32" hasn't managed to get enough recognition from sources that do high-quality hands-on testing and therefore didn't make it into any relevant roundups. That, by itself, makes it difficult to recommend.
Taking a look at the LG 27UD59 27", we found that it hasn't managed to perform well enough to earn a spot in any Monitor roundups done by sources that conduct their own, high-quality, hands-on testing. That alone makes it difficult to recommend.
As a last step, we wanted to do a head-to-head Samsung C32F391 32" vs. LG 27UD59 27" comparison of their review performance but, unfortunately, weren't able to find any review ratings on either product.