When comparing SFML vs PlayMaker + Unity3D, the Slant community recommends SFML for most people. In the question“What are the best 2D game engines?” SFML is ranked 35th while PlayMaker + Unity3D is ranked 77th.
Specs
Ranked in these QuestionsQuestion Ranking
Pros
Pro Very efficient and usable
Pro Zlib/PNG license
In short, SFML is free for any use (commercial or personal, proprietary or open-source). You can use SFML in your project without any restriction. You can even omit to mention that you use SFML -- although it would be appreciated.
Pro Can be combined with OpenGL
If you hate something about the way SFML handles graphics, you can just combine it with OpenGL. It's completely smooth and works as expected, without any additional dependencies.
Pro Active community and wiki
You can ask questions on their own personal forum which is full of users, and their wiki is constantly being maintained. They even have an IRC.
Pro Works on every platform
SFML 2.2 brought forth Android & iOS functionality, and SFML games work on Linux, Mac and Windows out of the box, since SFML is written with OpenGL.

Pro Great documentation
SFML is very well documented, even with short examples of use for many functions and modules. Furthermore, there are books like 'SFML essentials' and 'SFML for game development' which teach you how to use this library to its fullest.
Pro Good for OpenGL
If you are thinking about using OpenGL, look no further, you can open a window, and handle events in less than 15 lines, and it provides input, time, and even networking, plus alot more. It has become my favorite c++ library :D
Pro Great library
SFML is a collection of modular, well designed libraries you can implement an engine or game on top of. The API provides tons of good documentation and is very straightforward to use. You can get a game up and running with SFML quite quickly and with minimal effort.
Pro Clean code
An SFML project's code-base is usually clean and easy to read. All public SFML classes are under the namespace "sf" so it is easy to tell which code is yours and which belongs to SFML (of course you can stop this by typing using namespace sf;
).
Pro Available in many languages
There's support for many languages besides C++, current supported languages are: C, .NET, Crystal, D, Euphoria, Go, Java, Julia, Nim, OCaml, Pascal, Python, Ruby and Rust, and this list is constantly growing.
Pro Beginner-friendly
SFML is extremely beginner friendly and even provides pre-built libraries for your IDE of choice on Windows. Besides the fact that it's extremely well documented, they also have a set of tutorials that walk you through every module.
Pro Modern C++11 implementation
SFML is one of the few good C++ frameworks out there to actually make full use of the language. It's extremely well optimized and it plays well with anything you throw at it.
Pro Easy to use
You'll need to put more time in learning Unity + Playmaker compared to something like GameSalad. But once get the hang of it and familiarize yourself with what it's possible to build with them, it's quite easy to use.
Pro Provides access to a huge list of assets through Asset Store
For those developers who can't afford an artist, or aren't skilled enough to create their own art, Unity features an Asset Store full of a wide variety of free and paid assets that can be easily added to your game. The Asset Store has more than just music and art. It also has code and modules that can be added to your game such as unique lighting or GUI systems.
Pro Third party plugins support
A lot of third party plugins have support for Playmaker. Playmaker team also invest time to add support for a lot of third party plugins.

Pro Elegant state-based visual scripting
Instead of a single "if this then that" event list which can become very cluttered beyond the most basic behaviors, PlayMaker gives each object a list of states where only certain events are triggered, and performing an action also changes state.
This allows for a clean, simple visual representation which helps break complex logical structures into smaller pieces, making them easier to understand.

Pro Powerful
It basically can do same things as scripting in Unity.
Cons
Con Relatively slow
Compared to SDL2, GLFW, it is slow.
Con No GUI editor or IDE
Does not include any IDE or media editor. It's purely source code.
Con May take longer to learn and understand
Con Messy sprite management
Sprites retain all of the operations applied to them, whether that be a new position or a rotation. This makes sprite management somewhat annoying.
Con Not specifically a 2D game engine
It isn't really an engine, more of a collection of modular, well designed libraries you can implement an engine or game on top of.
Con Comparatively high learning curve
Although C#, JavaScript, and Boo have extensive documentation available online, it could still be difficult to wrap your head around the library and Unity's component based system.
Con Limited tutorials
There are not a lot videos with Playmaker tutorials. Official text tutorials are also quite limited. Even not every action has a description on an official wiki.
Con Performance could be better for 2D
Performance can be a real issue with 2D games. Unity 3D is actually a 3D game engine, and drags a lot of overhead with it.
For mobile, one could never achieve the performance of more specialized 2D engines with Unity3D.
