When comparing SteamOS vs KDE Neon, the Slant community recommends KDE Neon for most people. In the question“What are the best Linux distributions for desktops?” KDE Neon is ranked 36th while SteamOS is ranked 79th. The most important reason people chose KDE Neon is:
Since it's built on the strong Ubuntu base, KDE Neon works seamlessly with a huge variety of hardware.
Specs
Ranked in these QuestionsQuestion Ranking
Pros
Pro Native graphics processor support
The OS natively supports Nvidia, Intel, and AMD graphics processors.
Pro Streaming service integration (under development)
Valve is in talks with streaming companies such as Spotify and Netflix to bring their features to SteamOS.
Pro For entertainment, it just works
What media center software do for videos, it does for games (and later videos).
Pro Works out of the box
Since it's built on the strong Ubuntu base, KDE Neon works seamlessly with a huge variety of hardware.
Pro Configurability
KDE Neon uses KDE as its desktop environment, which is highly configurable, but also has great defaults.
Pro The best looking Linux OS
It really is a great and stunning looking OS.
Pro Works well on low-end computers
Cons
Con Hard to install
If you've installed Arch you're probably fine, but for those used to simple installs like (Ubuntu to name just one) you should prepare some patience, determination, and painkillers. Good news is, it's getting better (it's very young).
Con Not built around the desktop experience
SteamOS is, first and foremost, meant to act as a gaming console - it doesn't ship with even some of the most basic applications, such as a file manager or image viewer. As a result, using SteamOS as your primary operating system would require a fair bit of work.
Con Steep learning curve for beginners
It's a really sparse, bare-bones system, no automatic driver install for example. It can be quite hard for someone not used to Linux.