When comparing Google Hangouts vs Plex, the Slant community recommends Plex for most people. In the question“What are the most useful Android phone apps?” Plex is ranked 20th while Google Hangouts is ranked 31st. The most important reason people chose Plex is:
It's pretty hard to find a NAS or STB that doesn't support Plex.
Specs
Ranked in these QuestionsQuestion Ranking
Pros
Pro Mobile support
Hangouts offers both an Android and iOS app so users can participate from nearly any mobile device in addition to his Desktop.
Pro Screen sharing
Any user can share his screen (or only a specific desktop or window) while still continuing an audio conversation.
Pro Free group video support
Hangouts works with up to 10 participants using video out of the box or up to 15 if you are a business, government or school. It determines who is the primary speaker at any given time, and the camera view automatically switches to that user.
Pro Useful for businesses
Hangouts can scale to become a videoconferencing solution for an entire company, since the software can run on nearly all platforms. In fact, Google itself uses Hangouts as its meeting room video conference software.
Pro Easy to start using
Hangouts is integrated with Gmail & Google+, does not require you to download desktop software, and all chats can take place directly in your browser, significantly reducing the barrier to entry for a new user.
Pro Completely free
Google offers all features of Hangouts completely free. There are business, education and government solutions that increase the participant count to for video calls to 15 and offers support.
Pro Cross platform
Hangouts work on Android, iOS, Chrome OS, web and as a Chrome extension.
Pro Live broadcasting and instant recording
With Google+ “Hangouts on Air”, you can broadcast any hangout to an unlimited audience via your Goolge+ Profile or simply a generic YouTube link. Moreover, any Hangout on Air (public or private) is automatically saved as YouTube video that you can keep for private reference or use in any way that you would normally share a YouTube video. This allows you to record conversations without additional obtrusive software.
Pro Google Voice integration
Allows for a fixed phone number, receiving and making calls. Calling US or Canada is free.
Pro Integrates with Google Maps for sharing locations
When chatting with people while trying to plan a meet up, the share map button can be extremely useful.
Pro Android app does both sms and hangouts messaging
Pro Supported on many devices
It's pretty hard to find a NAS or STB that doesn't support Plex.
Pro Accessible via web browser
A modern web browser is enough to get everything Plex has to offer.
Pro Added lots of media databases
Metadata for media files will automatically be updated by using media databases. This provides posters, movie trailers, descriptions, information about actors, etc.
Cons
Con Poor video call quality
Only goes up to 720p30 + low bitrate.
Con Owned by Google
Con Lacking clients for older versions
Con High hardware usage
Con Not recommended for long sessions

Con Won't work on Windows 8-style UI
As Hangouts uses a browser plugin on the desktop and it doesn't work with Windows 8-style UI, it has to be used in desktop mode.
Con Needs registration
You need a PLEX account even if you use it on your local LAN.
Con Proprietary software
Unfree software.
Con No gapless audio-playback
Plex still does not support gapless playback of audio files such as mp3 or FLAC.
Con Playback error: This server is not powerful enough to convert video
More hardware requirements on Plex due to a useless/non-intuitive transcoder. When using lower spec hardware (eg SBC) Plex will not transcode or play HD+ videos. When compared to other packages (eg Jellyfin which transcodes nicely using FFMeg), Plex falls short on video playback and transcode settings to get videos to play (fastest/lightest option still fails).
