SteamOS is, first and foremost, meant to act as a gaming console - it doesn't ship with even some of the most basic applications, such as a file manager or image viewer. As a result, using SteamOS as your primary operating system would require a fair bit of work.

If you've installed Arch you're probably fine, but for those used to simple installs like (Ubuntu to name just one) you should prepare some patience, determination, and painkillers. Good news is, it's getting better (it's very young).